Dual Metal-Loaded Porous Carbon Materials Derived from Silk Fibroin as Bifunctional Electrocatalysts for Hydrogen Evolution Reaction and Oxygen Evolution Reaction
Category
Topical Literature Review
Department
Material Science
Student Status
Graduate
Research Advisor
Dr. Ram Gupta
Document Type
Event
Location
Student Center Ballroom
Start Date
10-4-2025 2:00 PM
End Date
10-4-2025 4:00 PM
Description
Developing electrocatalysts with high efficiency and long-term stability for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is significant to massively generate hydrogen energy by water splitting. In this work, cobalt and tungsten dual metal-loaded N-doped porous carbon electrocatalysts derived from silk fibroin were successfully prepared through facile carbonization and chemical activation by KCl and applied as efficient electrocatalysts for HER and OER. After chemical activation, the resulting catalysts present a unique hierarchical porous structure with micro-, meso-, and macropores, which can expose more implantation sites for catalytic active metals and will in turn promote the efficient diffusion of the electrolyte. The catalyst under the optimized condition (CoW@ACSF) has a specific area of 326.01 m2 /g. The overpotential at a current density of 10 mA/cm2 of CoW@ACSF is 138.42 ± 10.39 mV toward HER and 492.05 ± 19.04 mV toward OER. Furthermore, the overpotential only increases 101.2 mV toward HER and 66.00 mV toward OER after the long-term stability test of chronopotentiometric test over 10 h, which confirms the excellent stability of the CoW@ACSF, owing to its unique carbon shell structure. This work gives an insight into the design and engineering of silk fibroin-derived carbon materials for electrocatalysis toward HER and OER.
Dual Metal-Loaded Porous Carbon Materials Derived from Silk Fibroin as Bifunctional Electrocatalysts for Hydrogen Evolution Reaction and Oxygen Evolution Reaction
Student Center Ballroom
Developing electrocatalysts with high efficiency and long-term stability for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is significant to massively generate hydrogen energy by water splitting. In this work, cobalt and tungsten dual metal-loaded N-doped porous carbon electrocatalysts derived from silk fibroin were successfully prepared through facile carbonization and chemical activation by KCl and applied as efficient electrocatalysts for HER and OER. After chemical activation, the resulting catalysts present a unique hierarchical porous structure with micro-, meso-, and macropores, which can expose more implantation sites for catalytic active metals and will in turn promote the efficient diffusion of the electrolyte. The catalyst under the optimized condition (CoW@ACSF) has a specific area of 326.01 m2 /g. The overpotential at a current density of 10 mA/cm2 of CoW@ACSF is 138.42 ± 10.39 mV toward HER and 492.05 ± 19.04 mV toward OER. Furthermore, the overpotential only increases 101.2 mV toward HER and 66.00 mV toward OER after the long-term stability test of chronopotentiometric test over 10 h, which confirms the excellent stability of the CoW@ACSF, owing to its unique carbon shell structure. This work gives an insight into the design and engineering of silk fibroin-derived carbon materials for electrocatalysis toward HER and OER.
