Developing FeCo-NC Alloy For Optimizing Electrocatalytic Activity In Water Splitting And Oxygen Reduction

Category

Sciences and Technology

Department

Material Science

Student Status

Graduate

Research Advisor

Dr. Ram K. Gupta

Document Type

Event

Location

Sunflower

Start Date

10-4-2025 9:30 AM

End Date

10-4-2025 9:50 AM

Description

With the increasing demand for sustainable energy, developing efficient electrocatalysts for key reactions like the oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and oxygen reduction reaction (ORR) is crucial. This study explores the design of a FeCo-NC/CNT alloy catalyst with tunable Fe/Co ratios to enhance catalytic performance. The catalyst was synthesized using hydrothermal and pyrolysis methods, forming a well-structured alloy supported by nitrogen-doped carbon. Characterization confirmed the successful integration of Fe and Co into the NC/CNT framework, improving conductivity and increasing active sites for reactions. Electrochemical tests showed that the Fe0.9Co0.1-CNT catalyst exhibited the best performance, with an OER overpotential of 247 mV, an HER overpotential of 71 mV at 10 mA/cm2 , and an ORR half-wave potential (E1/2) of 0.87 V vs. RHE. Its OER activity is comparable to iridium oxide, a standard noble metal catalyst, highlighting its potential as a cost-effective and efficient alternative. The synergy between Fe and Co in the NC/CNT matrix enhances reaction kinetics and electron transfer, making this catalyst a strong candidate for fuel cells, metal-air batteries, and water-splitting applications. This research emphasizes the importance of optimizing metal composition and catalyst structure to develop high-performance, affordable electrocatalysts, contributing to the advancement of sustainable energy technologies.

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Apr 10th, 9:30 AM Apr 10th, 9:50 AM

Developing FeCo-NC Alloy For Optimizing Electrocatalytic Activity In Water Splitting And Oxygen Reduction

Sunflower

With the increasing demand for sustainable energy, developing efficient electrocatalysts for key reactions like the oxygen evolution reaction (OER), hydrogen evolution reaction (HER), and oxygen reduction reaction (ORR) is crucial. This study explores the design of a FeCo-NC/CNT alloy catalyst with tunable Fe/Co ratios to enhance catalytic performance. The catalyst was synthesized using hydrothermal and pyrolysis methods, forming a well-structured alloy supported by nitrogen-doped carbon. Characterization confirmed the successful integration of Fe and Co into the NC/CNT framework, improving conductivity and increasing active sites for reactions. Electrochemical tests showed that the Fe0.9Co0.1-CNT catalyst exhibited the best performance, with an OER overpotential of 247 mV, an HER overpotential of 71 mV at 10 mA/cm2 , and an ORR half-wave potential (E1/2) of 0.87 V vs. RHE. Its OER activity is comparable to iridium oxide, a standard noble metal catalyst, highlighting its potential as a cost-effective and efficient alternative. The synergy between Fe and Co in the NC/CNT matrix enhances reaction kinetics and electron transfer, making this catalyst a strong candidate for fuel cells, metal-air batteries, and water-splitting applications. This research emphasizes the importance of optimizing metal composition and catalyst structure to develop high-performance, affordable electrocatalysts, contributing to the advancement of sustainable energy technologies.